cis-Dinitratodiammineplatinum(II), cis-Pt(NH3)2 (NO3)2.  Crystalline structure and vibrational spectra

Lippert, Bernhard; Lock, C. J. L.; Rosenberg, Barnett; Zvagulis, M.

doi:10.1021/ic50172a057

Cited by 103 publications

(47 citation statements)

References 6 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…intensities were also measured with use of the Nicolet P3 diffractomcter and a coupled 8(crystal)-28(counter) scan. The methods of selection of scan rates and initial data treatment have been describcd (9,10). Corrections were made for Lorentz polarization effects but not for absorption.…”

Section: Spectral Measurementmentioning

confidence: 99%

Structural and spectroscopic studies of dipotassium 3,3,3′,3′-tetramethylcystinate trihydrate, K₂[C₁₀H₁₈N₂O₄S₂]3H₂O

Faggiani¹,

Howard-Lock²,

Lock³

et al. 1984

Can. J. Chem.

View full text Add to dashboard Cite

127 (1984). The compound dipotassium 3,3,3',3'-tetramethylcystinate trihydrate, K2 [CII,H,,0,N2S2]3H20, has been prepared and characterized by single crystal X-ray diffraction. Crystals were monoclinic, P 2 , , n = 6.160(1), b = 26.473(8), c = 6.193(1) A, P = 113.94(1)", with two formula units in the unit cell. Intensities were measured on a Syntex P2[ diffractometer with use of MoKa radiation. The structure was solved by standard methods and refined to RI = 0.0469, R2 = 0.0472 based on 2303 independent observed reflections. The C-S bonds (1.877(6), 1.891(6) A) are longer than in many similar compounds although the S-S bond (2.040(2) A) is not. The C-S-S-C torsional angle (108.7(3)") is larger than normal in dithiol compounds. Other distances and angles are normal. Two types of potassium coordination are present, one a distorted octahedron, the other a distorted trigonal prism. In addition to the ionic interactions, hydrogen bonds involving the water molecules are important in stabilizing the structure. (108,7(3)") est plus grand que ceux observts normalement dans les dithiols. Les autres distances et les autres angles sont normaux. Le potassium posskde deux types de coordination, I'un est un octakdre deform6 tandis que I'autre est un prisme trigonal dCformC. En plus des interactions ioniques, les liaisons hydrogknes impliquant les molCcules d'eau sont importantes pour de la stabilitC de la structure.[Traduit par le journal]

show abstract

Section: Spectral Measurementmentioning

confidence: 99%

Structural and spectroscopic studies of dipotassium 3,3,3′,3′-tetramethylcystinate trihydrate, K₂[C₁₀H₁₈N₂O₄S₂]3H₂O

Faggiani¹,

Howard-Lock²,

Lock³

et al. 1984

Can. J. Chem.

View full text Add to dashboard Cite

show abstract

“…Two standard reflections were monitored; there was no perceptible drift in their intensities and no one standard measurement differed by more than 2% from the mean. The raw data were reduced according to Lippart, Lock, Rosaberg & Zvagolis (1977). 5868 unique reflections * We are grateful to Professor C. J. L. Lock for arranging, and to R. Faggiani for carrying out data collection at the Department of Materials Science, McMaster University, Hamilton, Canada L8S 4L8.…”

mentioning

confidence: 99%

Structure of 2-(1-adamantyl)-2-trimethylsiloxy-1,1-bis(trimethylsily)-1-silaethylene

Nyburg¹,

Brook²,

Abdesaken³

et al. 1985

Acta Crystallogr C

View full text Add to dashboard Cite

“…Intensity data were also recorded on the Syntex P21 diffractometer using a coupled 0(crystal)-20(counter) scan. The methods of selection of scan rates and initial data treatment have been described (Lippert, Lock, Rosenberg & Zvagulis, 1977;Hughes, Krishnamachari, Lock, Powell & Turner, 1977). Corrections were made for Lorentz-polarization effects.…”

Section: Collection Of the X-ray Datamentioning

confidence: 99%

Tris[cis-dichloro(1,2-diaminocyclohexane)-platinum(II)] hydrate and cis-dibromo(1,2-diaminocyclohexane)platinum(II)

Lock¹,

Pilon²

1981

Acta Crystallogr Sect B

Self Cite

View full text Add to dashboard Cite

cis-Dinitratodiammineplatinum(II), cis-Pt(NH3)2 (NO3)2. Crystalline structure and vibrational spectra

Cited by 103 publications

References 6 publications

Structural and spectroscopic studies of dipotassium 3,3,3′,3′-tetramethylcystinate trihydrate, K₂[C₁₀H₁₈N₂O₄S₂]3H₂O

Structural and spectroscopic studies of dipotassium 3,3,3′,3′-tetramethylcystinate trihydrate, K₂[C₁₀H₁₈N₂O₄S₂]3H₂O

Structure of 2-(1-adamantyl)-2-trimethylsiloxy-1,1-bis(trimethylsily)-1-silaethylene

Tris[cis-dichloro(1,2-diaminocyclohexane)-platinum(II)] hydrate and cis-dibromo(1,2-diaminocyclohexane)platinum(II)

Contact Info

Product

Resources

About

cis-Dinitratodiammineplatinum(II), cis-Pt(NH3)2 (NO3)2. Crystalline structure and vibrational spectra

Cited by 103 publications

References 6 publications

Structural and spectroscopic studies of dipotassium 3,3,3′,3′-tetramethylcystinate trihydrate, K2[C10H18N2O4S2]3H2O

Structural and spectroscopic studies of dipotassium 3,3,3′,3′-tetramethylcystinate trihydrate, K2[C10H18N2O4S2]3H2O

Structure of 2-(1-adamantyl)-2-trimethylsiloxy-1,1-bis(trimethylsily)-1-silaethylene

Tris[cis-dichloro(1,2-diaminocyclohexane)-platinum(II)] hydrate and cis-dibromo(1,2-diaminocyclohexane)platinum(II)

Contact Info

Product

Resources

About

Structural and spectroscopic studies of dipotassium 3,3,3′,3′-tetramethylcystinate trihydrate, K₂[C₁₀H₁₈N₂O₄S₂]3H₂O

Structural and spectroscopic studies of dipotassium 3,3,3′,3′-tetramethylcystinate trihydrate, K₂[C₁₀H₁₈N₂O₄S₂]3H₂O