The diagnosis of Autism Spectrum Disorder (ASD) is typically based on behavioral observation, which is a process time-consuming, subjective and reliant on professional judgment. This study leverages research on salivary biomarkers to develop a tool capable of adding objectivity to this process. A high-level classifier based on complex networks was employed using different network formation methods based on Attenuated Total Reflection Fourier-Transform Infrared spectroscopy (ATR-FTIR) data from saliva samples. The results indicate the use of high-level classifiers as a promising tool for ASD detection.