Imbalance in hyperspectral images creates a crisis in its analysis and classification operation. Resampling techniques are utilized to minimize the data imbalance. Although only a limited number of resampling methods were explored in the previous research, a small quantity of work has been done. In this study, we propose a novel illustrative study of the performance of the existing resampling techniques, viz. oversampling, undersampling, and hybrid sampling, for removing the imbalance from the minor samples of the hyperspectral dataset. The balanced dataset is classified in the next step, using the tree-based ensemble classifiers by including the spectral and spatial features. Finally, the comparative study is performed based on the statistical analysis of the outcome obtained from those classifiers that are discussed in the results section. In addition, we applied a new ensemble hybrid classifier named random rotation forest to our dataset. Three benchmark hyperspectral datasets: Indian Pines, Salinas Valley, and Pavia University, are applied for performing the experiments. We have taken precision, recall, F score, Cohen kappa, and overall accuracy as assessment metrics to evaluate our model. The obtained result shows that SMOTE, Tomek Links, and their combinations stand out to be the more optimized resampling strategies. Moreover, the ensemble classifiers such as rotation forest and random rotation ensemble provide more accuracy than others of their kind.