Clay supported redox catalysts

Davison, Nigel; McWhinnie, William R.

doi:10.1016/s0020-1693(00)87898-6

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1987

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ChemInform Abstract: Clay Supported Redox Catalysts.

Davison¹,

McWhinnie²

1987

ChemInform

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083ChemInform Abstract Hectorite, a Li-Mg smectite, is exchanged to the sodium form, then reacted with CoCl2 solution and finally treated with 2,2'-bipyridyl in ethanol. (Co(bipy)3)3+/hectorite thus obtained is reduced either electrochemically (flocculated onto the surface of a Pt electrode) or chemically with NaBH4. The (Co(bipy)3)+/hectorite generated by NaBH4 reduces nitrobenzene either with or without NaBH4 presentto aniline (100% conversion in the presence of NaBH4).

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