A catalyst with 0.7 wt% Pd load supported over Co 3 O 4 oxide was investigated in the methane oxidation by operating under CH 4 /O 2 stoichiometric conditions. The effect of the noble metal addition on the activity of bare Co 3 O 4 was evaluated. Samples were characterized by BET, XRD, TPR and XPS analyses. The SO 2 poisoning of Pd catalyst and Co 3 O 4 was studied by performing CH 4 oxidation tests under stoichiometric conditions in SO 2 (1 ppm or 10 ppm) . Experiments evidenced that in our conditions the low amount of SO 2 doesn't influence the Pd behaviour, whereas in presence of 10 ppm of SO 2 some deactivation occurs that becomes more evident above 450°C at which the catalyst doesn't reach 100% of methane conversion. Catalytic tests performed over Co 3 O 4 and the Pd supported catalyst, after a treatment at 350°C for 15 h in 10 ppm SO 2 /He, suggest that Co 3 O 4 is a sulphating support, as confirmed by XPS analysis. Therefore, an important role in lowering the sulphur poisoning of Pd may be played by Co 3 O 4 .