Clicking beyond suspensions: understanding thiol–ene chemistry on solid-supported MoS<sub>2</sub>

Rodríguez González, Miriam C.; Ibarburu, Iván M.; Rebanal, Clara; Sulleiro, Manuel Vázquez; Sasikumar, Rahul; Naranjo, Alicia; Ayani, Cosme G.; Garnica, Manuela; Calleja, Fabián; Pérez, Emilio M.; Vázquez de Parga, Amadeo L.; De Feyter, Steven

doi:10.1039/d3nr05236b

Nanoscale

2024

DOI: 10.1039/d3nr05236b

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Clicking beyond suspensions: understanding thiol–ene chemistry on solid-supported MoS₂

Miriam C. Rodríguez González,

Iván M. Ibarburu,

Clara Rebanal

et al.

Abstract: The molecular functionalization of MoS2 has attracted a lot of attention due to its potential to afford fine-tuned hybrid materials that benefit from the power of synthetic chemistry and molecular...

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Scope and Limitations of Using Microemulsions for the Covalent Patterning of Graphene

Naranjo,

Garrido,

Martín Sabanés

et al. 2024

Chemistry A European J

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Patterning of graphene (functionalizing some areas while leaving others intact) is challenging, as all the C atoms in the basal plane are identical, but it is also desirable for a variety of applications, like opening a bandgap in the electronic structure of graphene. Several methods have been reported to pattern graphene, but most of them are very technologically intensive. Recently, we reported the use of microemulsions as templates to pattern graphene at the µm scale. This method is very simple and in principle tunable, as emulsions of different droplet size and composition can be prepared easily. Here, we explore in detail the scope of this methodology by applying it to all the combinations of four different emulsions and three different organic reagents, and characterizing the resulting substrates exhaustively through Raman, SEM and AFM. We find that the method is general, works better when the reactive species are outside the micelles, and requires reactive species that involve short reaction times.

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Scope and Limitations of Using Microemulsions for the Covalent Patterning of Graphene

Naranjo,

Garrido,

Martín Sabanés

et al. 2024

Chemistry A European J

Self Cite

View full text Add to dashboard Cite

show abstract

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Clicking beyond suspensions: understanding thiol–ene chemistry on solid-supported MoS₂

Abstract: The molecular functionalization of MoS2 has attracted a lot of attention due to its potential to afford fine-tuned hybrid materials that benefit from the power of synthetic chemistry and molecular...

Cited by 1 publication

References 33 publications

Scope and Limitations of Using Microemulsions for the Covalent Patterning of Graphene

Scope and Limitations of Using Microemulsions for the Covalent Patterning of Graphene

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Clicking beyond suspensions: understanding thiol–ene chemistry on solid-supported MoS2

Abstract: The molecular functionalization of MoS2 has attracted a lot of attention due to its potential to afford fine-tuned hybrid materials that benefit from the power of synthetic chemistry and molecular...

Cited by 1 publication

References 33 publications

Scope and Limitations of Using Microemulsions for the Covalent Patterning of Graphene

Scope and Limitations of Using Microemulsions for the Covalent Patterning of Graphene

Contact Info

Product

Resources

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Clicking beyond suspensions: understanding thiol–ene chemistry on solid-supported MoS₂