“…In such cases, in order to improve the prediction of the L–W function, the equilibrium contact angle should be replaced with a dynamic contact angle. The result has been confirmed by several studies using molecular dynamics simulations. , Researchers have proposed several dynamic contact angle models, which can be classified into four categories: hydrodynamic models, molecular kinetic models, molecular self-laying models, − and empirical models, among which the molecular self-laying models consider the existence of the precursor film and its effect on thin-film viscosity concerning the dynamic contact angle. At the microscopic scale, the precursor film affects the spreading rate of the liquid, which cannot be ignored during the determination of the contact angle; therefore, here, molecular self-laying models are used to describe the variation of the contact angle.…”