Stress-strain relation, stress-block parameters, and length effect of polymer concrete flexural compression members were experimentally investigated. For these purposes, a series of C-shaped polymer concrete specimens subjected to a flexural compressive load were tested. On the basis of the test results, we proposed an equation to predict stress-strain relation of polymer concrete. In this model, we took account of the slope of descending branch beyond the peak stress point of a single curve. The proposed equation was numerically integrated to compute the rectangular stress-block parameters. Computed b 1 was greater than the values prescribed in ACI 318 Code for cement concrete, and a 1 was about 0.85 that is similar to the value regulated in ACI. A series of Cshaped specimens were also tested to study the length effect. The test results were curve fitted to obtain parameters for the existing length effect equation.