2023
DOI: 10.1021/acs.inorgchem.3c02109
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(CN3H6)[FeIIFeIII(SO4)3(H2O)3]: A Framework Iron Sulfate with a Mixed S = 2 and S = 5/2 Honeycomb Lattice

Victoria A. Ginga,
Oleg I. Siidra,
Alexander A. Tsirlin
et al.

Abstract: A new guanidinium-templated hydrated iron sulfate, [CN 3 H 6 ][Fe II Fe III (SO 4 ) 3 (H 2 O) 3 ] (1), was prepared from strongly acidic aqueous solutions. Its crystal structure is comprised from Fe III O 6 and Fe II O 3 (H 2 O) 3 octahedra linked by sulfate bridges forming a [Fe II Fe II (SO 4 ) 3 (H 2 O) 3 ] − 3D framework with a layer-bylayer ordering of ferric and ferrous cations. The structural topology of the framework is related to the anhydrous rhombohedral mikasaite Fe 2 (SO 4 ) 3 . The removal of par… Show more

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