CO Adsorbents Based on the Formation of a Supported Cu(CO)Cl Complex

Peng, Xing; Golden, T. C.; Pearlstein, Ronald M.; Pierantozzi, Ronald

doi:10.1021/la00002a028

Cited by 20 publications

(12 citation statements)

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“…The reactivity of CuCl with CO has been recognized since the 19th century. Solutions of CuCl readily absorb carbon monoxide at CO pressures of under 1 atm . The adduct that is formed, CuCl(CO), has a sheetlike structure.…”

Section: Copper(i) Carbonylsmentioning

confidence: 99%

Structure and Bonding in Copper(I) Carbonyl and Cyanide Complexes

Pike

2012

Organometallics

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The coordination chemistry of copper(I) carbonyls and cyano complexes is reviewed. Primary attention is focused structural chemistry, including coordination behavior, bridging modes, network formation, flexible coordination number, and reversible ligand binding. Additional coverage of infrared spectroscopy and orbital interactions in carbonyl and cyanide bonding, and photophysical behavior of metal cyano complexes is also included. BRIEF The coordination chemistry of copper(I) carbonyls and cyanide complexes is reviewed.

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Section: Copper(i) Carbonylsmentioning

confidence: 99%

Structure and Bonding in Copper(I) Carbonyl and Cyanide Complexes

Pike

2012

Organometallics

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“…The cause for such a favorable effect of copper(I) halide may be attributed to the ability of this halide to combine reversibly with CO and C 2 H 4 [3,11,12]. Although it is known that Cu itself is capable of adsorbing CO in the linear form in the highly negative potential range )1.5 to )1.0 V vs SCE [13], the adsorbing ability of copper(I) halides are considered to be much larger than that of Cu in consideration of the enhanced yield of ethylene with halides.…”

Section: Reduction Of Co 2 On a Copper(i) Halide-modified Cu-mesh Elementioning

confidence: 99%

Selective electrochemical reduction of CO2 to ethylene at a three-phase interface on copper(I) halide-confined Cu-mesh electrodes in acidic solutions of potassium halides

Yano

Tanaka

Nakayama

et al. 2004

Journal of Electroanalytical Chemistry

137

112

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“…Copper(I) carbonyls have long been of interest to chemists . They are formed in many catalytic transformations of CO and in the purification of CO from steam-methane-reforming gases . In addition, CO is used as a probe ligand for studying reduced copper-containing proteins and enzymes .…”

mentioning

confidence: 99%

Cu(CO)₂(N(SO₂CF₃)₂). The First Structurally Characterized Copper(I) Polycarbonyl

et al. 1999

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nate Cu + ion bonded to the sulfonamide nitrogen atom and to two CO ligands with long Cu-C bonds (1.90 and 1.91 Å) and a C-Cu-C bond angle of 122°. The two ν(CO) IR bands for this compound are at 2158 (s) and 2184 (m) cm -1 .Copper(I) carbonyls have long been of interest to chemists. 1 They are formed in many catalytic transformations of CO 2 and in the purification of CO from steam-methane-reforming gases. 3 In addition, CO is used as a probe ligand for studying reduced coppercontaining proteins and enzymes. 4 Finally, the ν(CO) values of copper(I) carbonyls can be either higher or lower than 2143 cm -1 , the value for gaseous CO. This makes copper(I) carbonyls of pivotal importance in understanding and refining the distinction between classical and nonclassical metal carbonyls. 5 Virtually all copper(I) carbonyl complexes studied to date have a stoichiometry Cu:CO ) 1:1. 6 Nevertheless, there are some important exceptions. In a seminal paper in 1976, Souma and co-workers reported that Cu + ions dissolved in strong protic acids could absorb up to 4(1) (a) Leblanc, F.

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CO Adsorbents Based on the Formation of a Supported Cu(CO)Cl Complex

Cited by 20 publications

References 0 publications

Structure and Bonding in Copper(I) Carbonyl and Cyanide Complexes

Structure and Bonding in Copper(I) Carbonyl and Cyanide Complexes

Selective electrochemical reduction of CO2 to ethylene at a three-phase interface on copper(I) halide-confined Cu-mesh electrodes in acidic solutions of potassium halides

Cu(CO)₂(N(SO₂CF₃)₂). The First Structurally Characterized Copper(I) Polycarbonyl

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CO Adsorbents Based on the Formation of a Supported Cu(CO)Cl Complex

Cited by 20 publications

References 0 publications

Structure and Bonding in Copper(I) Carbonyl and Cyanide Complexes

Structure and Bonding in Copper(I) Carbonyl and Cyanide Complexes

Selective electrochemical reduction of CO2 to ethylene at a three-phase interface on copper(I) halide-confined Cu-mesh electrodes in acidic solutions of potassium halides

Cu(CO)2(N(SO2CF3)2). The First Structurally Characterized Copper(I) Polycarbonyl

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Cu(CO)₂(N(SO₂CF₃)₂). The First Structurally Characterized Copper(I) Polycarbonyl