2010
DOI: 10.1016/j.tca.2009.09.001
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Co-crystal of (R,R)-1,2-cyclohexanediol with (R,R)-tartaric acid, a key structure in resolution of the (±)-trans-diol by supercritical extraction, and the related ternary phase system

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Cited by 30 publications
(25 citation statements)
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“…Cocrystallization typically relies on strong intermolecular interactions, such as hydrogen and halogen bonding, which are more universal. Cocrystallization has been explored by us and others in the context of chiral resolution to target several racemic drug systems . On the basis of these methods, and drawing a parallelism to CIDT, we set out to go beyond chiral resolution, targeting a cocrystallization‐induced spontaneous deracemization (CoISD) process.…”
Section: Methodsmentioning
confidence: 99%
See 1 more Smart Citation
“…Cocrystallization typically relies on strong intermolecular interactions, such as hydrogen and halogen bonding, which are more universal. Cocrystallization has been explored by us and others in the context of chiral resolution to target several racemic drug systems . On the basis of these methods, and drawing a parallelism to CIDT, we set out to go beyond chiral resolution, targeting a cocrystallization‐induced spontaneous deracemization (CoISD) process.…”
Section: Methodsmentioning
confidence: 99%
“…Cocrystallization has been explored by us and others in the context of chiral resolution to target several racemic drug systems. [22][23][24][25] On the basis of these methods, and drawing a parallelism to CIDT, we set out to go beyond chiral resolution, targeting a cocrystallization-induced spontaneous deracemization (CoISD) process. The industrially friendly thermodynamic process developed in this study is applicable to all compounds, whether they form salts or not, and to both conglomerate-and racemic-compound-forming systems, thereby making it a general process, in contrast to all other crystallization-based deracemization processes.…”
mentioning
confidence: 99%
“…Therefore thermal analysis is a common part of characterizing compounds with biological activity [20,21,22,23,24,25]. Thermoanalytical methods provide important information on the thermal stability, polymorphic forms or structural changes [26,27,28], and purity of potential new drugs [29,30,31,32]. In continuation of our earlier work on synthesis, physical and chemical characterization of iron(II) complexes with amine ligands [33] in this paper Pt(II) coordination compounds with different amine ligands are described.…”
Section: Introductionmentioning
confidence: 93%
“…However, such a complex structure determines the superior physicochemical properties of ternary eutectic composition than the binary one, which also efficiently reduces the drug side effects. 22 24 Therefore, it is particularly essential to acquire the related information about the micromolecular structural changes during the formation process of such ternary eutectics and/or co-crystals.…”
Section: Introductionmentioning
confidence: 99%