In order to understand the performance of waterflooding in nano-darcy permeability, naturally fractured shale reservoirs, an integrated study of spontaneous imbibition has been performed. In this study, oil recovery during spontaneous imbibition in naturally fractured shale samples was improved using different water formulations. Different water solutions were formulated by adding different amounts of HCl and NaOH to either distilled water or 2 wt% KCl-base brine solution. Eight water formulations, distilled water, 2% KCl brine, low pH HCl solutions (0.74-1.2), and high pH alkaline solutions (11.7-12.4) were examined to recover oil from shale rocks. Reservoir core samples from Eagle Ford shale were used in this study. The samples were 2.54 to 3.81 cm in diameter and 0.762 to 5.08 cm in length. Firstly, we studied the porosity of the used samples using CT Scanning. The average porosity was 1.6% for Eagle Ford shale samples. Secondly, we studied the rock stability and spontaneous imbibtion of the different Eagle Ford samples in distilled water, 2 wt% KCl, low pH solutions (0.74-1.2), and high pH alkaline solutions (11.7-12.4). During the spontaneous imbibition, the maximum oil recovery was 37% for Eagle Ford using pH 0.74 (3 wt% HCl in 2 wt% KCl) and 44% using pH 11.7 (0.1 wt% NaOH in distilled water). The oil recovery was improved by mineral dissolution using low and high pH solutions along with wettability alteration. The rock hardness was significantly affected by using both high and low pH solutions, which resulted in 93-98% loss of its initial value.
IntroductionIn shale reservoirs, oil is stored in a very tight matrix, with virtually all permeability concentrated in a large number of natural fractures (Fakcharoenphol et al. 2012). Due to these fractures, oil cannot be displaced from the matrix by means of conventional waterflooding. Channeling and bypassing through the fractures would result in extremely poor recovery (Guo et al. 1998). Primary oil production from such fractured reservoirs in which the storage occurs in the matrix and flow happens in fractures can be divided into three stages: 1) production from the fracture network at early time; 2) production from the fracture network and rock matrix at intermediate time; and 3) production from the rock matrix at a later time (Guo et al. 1998). Early production from the fracture network of shale formation declines rapidly because of a variety of reasons: increasing effective stress, proppant fatigue due to stress cycling, and digenesis. Most of the recovery of the intermediate and long-term stages of production depends on spontaneous imbibition of brine into the rock matrix and expulsion of oil via the fracture face. Spontaneous imbibition can add significant amount of oil recovery in fractured reservoirs with low matrix permeability depending on rock wetness quality. The rate of imbibition is mainly affected by the net effect of capillary pressure driving force and the opposing viscous resistance to flow. Because of the strong capillary forces, the small...