Co-generation of palladium nanoparticles and phosphate supported on metal–organic frameworks as hydrogenation catalysts

Takashima, Yohei; Tetsusashi, Seiko; Takano, Mai; Tanaka, Shintaro; Murakami, Yûichi; Tsuruoka, Takaaki; Akamatsu, Kensuke

doi:10.1039/d2dt04109j

Dalton Trans.

2023

DOI: 10.1039/d2dt04109j

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Co-generation of palladium nanoparticles and phosphate supported on metal–organic frameworks as hydrogenation catalysts

Yohei Takashima

Seiko Tetsusashi

Mai Takano

et al.

Abstract: In this study, we demonstrated the direct synthesis of sodium dihydrogen phosphate (PA) containing palladium nanoparticles (PdNPs) supported on a metal–organic framework (MOF). The resulting composite containing PA molecules coexisting...

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2024

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From Structure to Catalysis: Advances in Metal‐Organic Frameworks‐Based Shape‐Selective Reactions

Hooriabad Saboor,

Shahsavari,

Zandjou

et al. 2024

ChemNanoMat

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The presence of shape‐ and size‐selective catalysts in various catalytic reactions is of paramount importance. Metal‐organic frameworks (MOFs) possess a distinctive characteristic of lacking in‐accessible dead spaces, owing to their well‐structured nature. The effective separation of active sites within MOFs is facilitated by their exceptionally high surface area, which allows for a high density of active sites per unit volume of the catalyst. In this comprehensive review article, we delve into one of the most critical and practical features of MOFs: their ability to modify and engineer the structure of these materials. This structural engineering approach enables the attainment of desired physical, chemical, and surface properties, particularly in the realm of heterogeneous catalysts. The article encompasses several key areas, including surface functionalization within MOFs, synthesis of novel enzyme‐inspired MOFs, creation of mesoporous MOFs, development of porous structures utilizing MOFs, and engineering of structural limitations in MOFs. These rapidly advancing and highly applicable topics, especially in the field of heterogeneous catalysts, are thoroughly investigated and analyzed within the purview of this comprehensive review article.

show abstract

From Structure to Catalysis: Advances in Metal‐Organic Frameworks‐Based Shape‐Selective Reactions

Hooriabad Saboor,

Shahsavari,

Zandjou

et al. 2024

ChemNanoMat

View full text Add to dashboard Cite

show abstract

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Co-generation of palladium nanoparticles and phosphate supported on metal–organic frameworks as hydrogenation catalysts

Abstract: In this study, we demonstrated the direct synthesis of sodium dihydrogen phosphate (PA) containing palladium nanoparticles (PdNPs) supported on a metal–organic framework (MOF). The resulting composite containing PA molecules coexisting...

Cited by 1 publication

References 34 publications

From Structure to Catalysis: Advances in Metal‐Organic Frameworks‐Based Shape‐Selective Reactions

From Structure to Catalysis: Advances in Metal‐Organic Frameworks‐Based Shape‐Selective Reactions

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