[Co(phen3)]2[Cu11I15]: a mixed-metal iodocuprate containing the novel [Cu10I15]5− and [Cu12I15]3− clusters

Tripyridine‐Derivative‐Derived Semiconducting Iodo‐Argentate/Cuprate Hybrids with Excellent Visible‐Light‐Induced Photocatalytic Performance

“…The halide ions (Cl − , Br − , I − ) can serve as bridges from terminal to μ 2 ‐ and up to μ 8 ‐bridging. The combination of halide ions and different metal atoms, directed by various organic templates, has formed numerous captivating structures . Recently, Guo et al.…”

“…The combinationo fh alide ions and differentm etal atoms, directed by variouso rganic templates, has formedn umerous captivating structures. [38][39][40][41][42][43][44][45][46][47] Recently, Guo et al prepared as eries of chlorobismuthates and iodoplu-bates hybridsw ith excellent electronic conducting and luminescencep roperties. [11][12][48][49][50] Leia nd Yuee tal.…”

Synthesis and structural characterization of a novel copper(II)/lead(II) heterometallic organic–inorganic hybrid

“…Organic-inorganic hybrid compounds have attracted increasing interest due to their intriguing aesthetic structures [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15], as well as their interesting electrical, optical, and magnetic properties [2,[16][17][18][19][20][21]. One of the most extensively studied groups of organic-inorganic hybrid compounds is based on lead(II) halides, which are typically constructed from MX n polyhedra connected in corner-, edge-, or face-sharing arrangements [1, 3, 6-14, 17, 19-21].…”

A layered iodocuprate based on a 3D cationic supramolecular network of dimeric Co(ii) complexes by offset face-to-face interactions

“…6 As counterions to the iodocuprates, various organic cations, solvated metal cations and recently employed transition metal coordination cations, such as M(phen) 3 (M ¼ Fe, Co, Ni, etc. ), 7 can affect the nature of the anion motifs. Although the structural directing effects of various organic cations in the formation of oxide frameworks have been rationally studied, 8 comprehension of the directing effects of organic cations for non-oxide frameworks is still in an early stage.…”

“…The hydrogen atoms of coordinated water molecules have not been included in the final refinement. The Cu(3), Cu (7), Cu(8), I(1) atoms are disordered and split into two positions (Figure S6 †) in a ratio of 0.72 : 0.28, 0.70 : 0.30, 0.68 : 0.32, 0.55 : 0.45, according to the ''part'' commands.…”