Co-SBA-15 catalysts in the hydrolysis of NH3BH3 – Influences of Co precursors and catalyst pre-treatment

Herron, Rory; Marchant, Charles; Sullivan, James A.

doi:10.1016/j.catcom.2018.01.008

Cited by 10 publications

(1 citation statement)

References 23 publications

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“…The mesoporous silica materials, especially those with regular and well‐defined mesoporous channels and large specific surface area, such as MCM‐41, [ 169–171 ] KIT‐6, [ 167 ] FDU‐12, [ 168 ] and SBA‐15, [ 14a,161–166,188 ] were also widely used as supports to encapsulate active metal species for the solvolysis of AB. Chen and co‐workers prepared a series of bimetallic Cu‐Ni NPs with different molar ratios of Cu/Ni immobilized in MCM‐41 by using an impregnation‐reduction method.…”

Section: Catalytic Hydrogen Generation From Liquid‐phase Chemical Hydmentioning

confidence: 99%

Nanopore‐Supported Metal Nanocatalysts for Efficient Hydrogen Generation from Liquid‐Phase Chemical Hydrogen Storage Materials

et al. 2020

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Section: Catalytic Hydrogen Generation From Liquid‐phase Chemical Hydmentioning

confidence: 99%

Nanopore‐Supported Metal Nanocatalysts for Efficient Hydrogen Generation from Liquid‐Phase Chemical Hydrogen Storage Materials

et al. 2020

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Recent Progress on Cobalt‐Based Heterogeneous Catalysts for Hydrogen Production from Ammonia Borane

Li,

Gao,

et al. 2024

ChemCatChem

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Ammonia borane (NH3BH3, AB) is a quintessential exemplar of chemical hydrogen storage materials and has been widely used in hydrogen evolution. Although expensive metal catalysts (such as Rh, Ru, Pt, Ag, etc.) exhibit high activity in the hydrolysis of ammonia borane, inexpensive metals are more economical. Cobalt (Co), in particular, is not only relatively inexpensive and readily available, but also possesses high activity and selectivity. Compared to other catalysts, cobalt‐based catalysts have better durability and can maintain catalytic activity for a longer period of time, making them favored by researchers. These catalysts demonstrate excellent stability, hydrogen evolution rate, and turn over frequency. This article summarized previous progress in low price metal cobalt‐based catalysts for hydrogen precipitation from ammonia borane, focusing on cobalt‐based catalysts supported on various supports, especially those supported on carbon materials, metal oxides, MOFs, and nickel foams. The characteristics of high‐performance catalytic systems are analyzed in detail. The development prospects of Co catalysts for hydrogen production from ammonia borane were also discussed.

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Oxidative desulfurization strategies using Keggin-type polyoxometalate catalysts: Biphasic versus solvent-free systems

et al. 2019

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Co-SBA-15 catalysts in the hydrolysis of NH3BH3 – Influences of Co precursors and catalyst pre-treatment

Cited by 10 publications

References 23 publications

Nanopore‐Supported Metal Nanocatalysts for Efficient Hydrogen Generation from Liquid‐Phase Chemical Hydrogen Storage Materials

Nanopore‐Supported Metal Nanocatalysts for Efficient Hydrogen Generation from Liquid‐Phase Chemical Hydrogen Storage Materials

Recent Progress on Cobalt‐Based Heterogeneous Catalysts for Hydrogen Production from Ammonia Borane

Oxidative desulfurization strategies using Keggin-type polyoxometalate catalysts: Biphasic versus solvent-free systems

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