2024
DOI: 10.1021/acsapm.4c01446
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CO2–Philic Fluorinated Porous Organic Polyaminal in Photocatalytic Thiol–Ene Chemistry: Decoding the Effect of F-Atoms

Rupak Chatterjee,
Sudip Bhattacharjee,
Asim Bhaumik

Abstract: Achieving high uptake and efficient conversion of CO 2 under mild reaction conditions over metal-free porous organic material as a catalyst is very demanding in the context of CO 2 utilization reaction, which is highly sustainable and environmentally green. This is due to the fixation of abundant CO 2 as a renewable C1 source and its significant presence in the atmosphere as a primary greenhouse gas. Herein, we report three triazine-based porous organic polyaminals (POPAs) POPA-1, F-POPA-2, and 5F-POPA-3 throu… Show more

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