Co^(II)-doped hybrid Zn^(II) tetraborate complexes, [Zn_xCo_(1−x)(1,3-dap)B₄O₇] (1,3-dap = 1,3-diaminopropane): BET analysis and N₂/H₂O/D₂O adsorption studies

Abstract

A series of mono/bimetallic isostructural hybrid tetraborates of general formula [ZnxCo(1-x)(1,3-dap)B4O7] have been prepared by a solvothermal method. Their adsorption/desorption curves for H2O and D2O demonstrate that these materials have...