CO2 capture by piperazine mixed with non-aqueous solvent diethylene glycol in a rotating packed bed

Yu, Cheng-Hsiu; Wu, Tsai-Wei; Tan, Chung‐Sung

doi:10.1016/j.ijggc.2013.10.014

Cited by 52 publications

(22 citation statements)

References 29 publications

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“…The commercial name of the process that used this mixture as the solvent is Amisol process. Yu et al [160] proposed a non-aqueous mixture of PZ and diethylene glycol (DEG) in RPB. It was reported that the 40.8 wt% PZ could be dissolved in DEG at 20 o C without precipitation.…”

Section: Amine-alcoholmentioning

confidence: 99%

Role of solvents in CO2 capture processes: The review of selection and design methods

Borhani

Wang

2019

Renewable and Sustainable Energy Reviews

254

123

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Solvent selection and design are imperative in the CO2 capture process. The efficiency and the overall cost of the process are directly affected by the solvent as a consequence of the effect of solvent on factors such as CO2 absorption capacity, size of equipment, and solvent regeneration energy. This review paper aims to review the most important solvents and mixtures of solvents, absorbing CO2 via chemisorption, physisorption and chemi-physisoprtion. Characteristic and structure of different solvents are presented with the advantages and disadvantages of each being highlighted. Mixtures of solvents include chemical or physical solvents only, and combinations of physical and chemical solvents are categorised. In addition to common solvents, phase change solvents are also described. Once a comprehensive list of solvents is presented, different methods of solvent selection and design are illustrated, namely methods involving experiments, process and equilibrium models, predictive models, and computer-aided molecular design (CAMD). The importance of integrated solvent and process selection and design is also discussed. The most recent and selected progress studies in each section are reviewed in detail.

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Section: Amine-alcoholmentioning

confidence: 99%

Role of solvents in CO2 capture processes: The review of selection and design methods

Borhani

Wang

2019

Renewable and Sustainable Energy Reviews

254

123

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“…There are extensive studies in solvent selection from both academia and industry trying to identify alternative solvents for conventional PCC process. There are very few studies on PI using different solvents [85,87,89,121,[123][124][125][126]128,129,[148][149][150].…”

Section: Solvents Used For Intensified Pcc Processmentioning

confidence: 99%

“…PZ reacts rapidly with CO2 and thus has attracted interest for usage in CO2 capture, particularly as a reaction rate promoter for CO2 absorption in carbonate and tertiary amine solutions [148,[159][160][161][162]. Chemical reactions which describe the absorption of CO2 in PZ solutions are more complex than MEA [159,160].…”

Section: Piperazine (Pz)mentioning

confidence: 99%

Process intensification for post-combustion CO2 capture with chemical absorption: A critical review

et al. 2015

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The concentration of CO2 in the atmosphere is increasing rapidly. CO2 emissions may have an impact on global climate change. Effective CO2 emission abatement strategies such as carbon capture and storage (CCS) are required to combat this trend. Compared with pre-combustion carbon capture and oxy-fuel carbon capture approaches, post-combustion CO2 capture (PCC) using solvent process is one of the most mature carbon capture technologies. There are two main barriers for the PCC process using solvent to be commercially deployed: (a) high capital cost; (b) high thermal efficiency penalty due to solvent regeneration. Applying Process intensification (PI) technology into PCC with solvent process has the potential to significantly reduce capital costs compared with conventional technology using packed columns. This paper intends to evaluate different PI technologies for their suitability in PCC process. The study shows that rotating packed bed (RPB) absorber/stripper has attracted much interest due to its high mass transfer capability.Currently experimental studies on CO2 capture using RPB are based on standalone absorber or stripper. Therefore a schematic process flow diagram of intensified PCC process is proposed so as to motivate other researches for possible optimal design, operation and control. To intensify heat transfer in reboiler, spinning disc technology is recommended. To replace cross heat exchanger in conventional PCC (with packed column) process, printed circuit heat exchanger will be preferred. Solvent selection for conventional PCC process has been studied extensively. However, it needs more studies for solvent selection in intensified PCC process. The authors also predicted research challenges in intensified PCC process and potential new breakthrough from different aspects.

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“…To enhance the mass transfer between gaseous CO 2 and solution, an innovative modification of the absorption process has been proposed, for instance, a rotating packed bed (Tan and Chen, 2006;Lin et al, 2010). Besides that, various absorbent genomes have been proposed and evaluated to obtain high capture efficiency and low regeneration energy, such as using piperazine with diethylenetriamine (Yu et al, 2014), piperazine with diethylene glycol (Yu et al, 2013), and NaOH solution (Lin and Chu, 2015).…”

Section: Capturementioning

confidence: 99%

Challenges and Perspectives on Carbon Fixation and Utilization Technologies: An Overview

Ping

Pan

Pei

et al. 2016

Aerosol Air Qual. Res.

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This paper provides an overview of state-of-the-art carbon fixation and utilization technologies. Several carbon capture processes, such as chemical absorption and chemical looping, are reviewed and illustrated. In addition, various types of chemicals and fuels that can be produced using concentrated CO 2 (or other forms) through physical, chemical, or enhanced biological methods are presented. Among those carbon conversion methods, two promising approaches, i.e., microalgae ponds and accelerated carbonation using alkaline solid wastes, are reviewed in detail. Microalgae are fast-growing and ubiquitous photosynthetic organisms, which are rich in protein and can be converted to biodiesel fuel. They have been recognized as an alternative feedstock not only because they use CO 2 from the atmosphere but also due to their high lipid content per biomass compared to other plants. In this study, for the microalgae technologies, the principles and applications of open pond systems are discussed in terms of both technological and economic considerations. The important operation parameters affecting productivity of microalgae, including light intensity, temperature, mixing, CO 2 delivery, accumulation of dissolved oxygen, and salinity are summarized. On the other hand, accelerated carbonation technologies are an attractive and feasible approach to integrating alkaline solid waste treatment with CO 2 fixation and utilization. In this study, the performance of various carbonation processes is critically reviewed from the perspectives of process design, energy consumption, and environmental benefits. The carbonated solid product can also be used as supplementary cementitious materials in a blended cement or concrete block. Accordingly, the performance of cement pastes with carbonated product, in terms of workability and strength development, are evaluated from the cement chemistry point of view. Cement manufacturing is an energy and material intensive process, with high annual production. It is noted that, through the accelerated carbonation process, significant indirect environmental benefits can be realized.

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CO2 capture by piperazine mixed with non-aqueous solvent diethylene glycol in a rotating packed bed

Cited by 52 publications

References 29 publications

Role of solvents in CO2 capture processes: The review of selection and design methods

Role of solvents in CO2 capture processes: The review of selection and design methods

Process intensification for post-combustion CO2 capture with chemical absorption: A critical review

Challenges and Perspectives on Carbon Fixation and Utilization Technologies: An Overview

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