CdSe QDs with Cd 1−x Zn x Se shell structures were precipitated inside silicate glasses by continuous-wave laser irradiation (λ = 532 nm) without any heat-treatment process. Emission from the surface defects (λ ≈ 620 nm) was quenched significantly and the lifetimes of the band-edge emission was increased. During the laser irradiation, Zn ions were gradually incorporated into the outer region of CdSe QDs to form Cd 1−x Zn x Se (0.76 ≤ x ≤ 0.8) alloy shells.