Abstract-In this study the high-pressure caking behavior of large Waterberg coal particles (4, 8, 10 and 20mm) was investigated. This coal was density separated into the following fractions: FL1.3, FL1.5, FL1.7, FL 1.9 and SI 1.9. Small samples (10-20g) of the 4,8,10 and 20mm density separated lump coal were reacted in a high-pressure reactor at 4 different pressures (Atm, 7.5, 15, and 30bar) at fixed temperatures of 450°C and 550°C. A 7°C per minute heating rate was employed during all experiments, which was executed in an inert nitrogen atmosphere. The degree of caking was determined on a mass% basis. X-ray computed tomography scans were conducted on the high caking density fraction FL1.3 and parent coal. Conventional coal characterization (proximate and ultimate) and petrographic analysis before and after devolatilization of the 10mm density separated coal fraction was also conducted. Finally, a predictive caking model was developed based on the coal properties. The caking propensity was found to be higher under 30bar pressure than at atmospheric conditions (0.87bar) for the 10mm particles, subjected to density cuts (FL1.5 and FL1.7) and the parent coal. The FL1.3, FL1.9 and SI1.9 fractions reported the same caking propensities under both 30bar and atmospheric pressures. On the other hand, the 4 and 8mm particles reported higher caking propensities at 550°C than for 450°C at 0.87 and 30bar pressure respectively. The 20mm particles reported slightly higher caking propensities (5 % ) than for the 10mm particles at 30bar and 550°C. It was also found that the caking propensity reaches a maximum at 15bar pressure for the 10mm particles. It is concluded that as the coal fractional density increases the caking propensity decreases. From the x-ray micro focus tomography results it is clear that the porosity of the caked particles decreases and the coalescence of the particles increase as the pressure increases. From characterization analysis it was found that the lighter density cuts contain more volatile matter, a higher CV value, lower ash content and higher vitrinite maceral composition, leading to higher caking propensity.