2024
DOI: 10.1039/d4qo01057d
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COAP/Pd-catalyzed asymmetric linear allylic alkylation for synthesizing chiral 3,3′-disubstituted oxindoles bearing all-carbon quaternary stereocenters and primary allylic alcohol structures

Wen-Kai Liu,
Bai-Lin Wang,
Xing-Yun Sun
et al.

Abstract: A linear asymmetric allylic alkylation of 3-aryl oxindole derivatives with vinyloxirane was reported by using a chiral oxalamide–phosphine (COAP)/Pd(0) complex as a catalyst, which provided chiral 3,3′-oxindole derivatives containing all-carbon...

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