Cobalt(III) Schiff base complexes derived from mesostilbenediamine: Synthesis, characterization, crystal structure, electrochemistry and antibacterial studies

Circular Dichroism Sensing of Chiral Compounds Using an Achiral Metal Complex as Probe

“…). The most common trans ‐configuration in which the salen ligand resides in the meridional plane is the predominant species when monodentate ligands occupy the axial positions . The cis‐α and in particular the cis‐β configuration are favored when bidentate ligands are present …”

“…The most common trans-configuration in which the salen ligand resides in the meridional plane is the predominant species IRFANOGLU AND WOLF when monodentate ligands occupy the axial positions. 51,52 The cis-α and in particular the cis-β configuration are favored when bidentate ligands are present. 53,54 We therefore expected that coordination of a bidentate chiral compound such as a diamine or amino alcohol to a (meso-5)cobalt complex would force the salen ligand into a chiral, CD-active conformation.…”

New salen-type manganese(III) Schiff base complexes derived from meso-1,2-diphenyl-1,2-ethylenediamine: In vitro anticancer activity, mechanism of action, and molecular docking studies

“…We have previously synthesized and characterized different transition metal complexes of salen-type Schiff base ligands, especially those derived from meso-1,2-diphenyl-1,2-ethylenediamine and have studied their catalytic and biological properties [20][21][22][23][24][25][26][27][28][29][30]. In continuation of our previous studies, we report the synthesis and characterization of four new Mn(III) complexes with Schiff bases of general formula [MnClL x ] (x = 1-4).…”

“…Meso-1,2-diphenyl-1,2-ethylenediamine [31] and H 2 L n (n = 1-4) [20][21][22][23] were synthesized as described.…”

Crystal structures, spectroscopic, electrochemical, and antibacterial properties of a series of new copper(II) Schiff base complexes

“…Emails: mbehzad@semnan.ac.ir; mahdibehzad@yahoo.com Downloaded by [New York University] at 04: 18 28 May 2015 been used as models of biological compounds and have been key in the development of inorganic biochemistry [11]. Having all the above facts in mind, we focused on the synthesis and study of antibacterial activities of a series of transition metal Schiff base complexes [12][13][14][15]. In our previous studies, we found that the presence of more electronegative substituents on the salicylaldehyde moieties of the Schiff base ligands increased the antibacterial activity of their complexes.…”