Cobalt, Iron and Some of their Alloys as Catalysts for the Hydrogenation of Carbon Dioxide<sup>1</sup>

Stowe, Robert; Russell, W. Walker

doi:10.1021/ja01631a001

Cited by 15 publications

(10 citation statements)

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“…In an early study, Stowe and Russell used cobalt, iron, and some of their alloys as catalysts for the hydrogenation of carbon dioxide. Satthawong et al .…”

Section: Introductionsupporting

confidence: 93%

Hydrogenation of Carbon Dioxide over K‐Promoted FeCo Bimetallic Catalysts Prepared from Mixed Metal Oxalates

et al. 2017

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The hydrogenation of carbon dioxide over K‐promoted FeCo bimetallic catalysts prepared by sequential oxalate decomposition and carburization of FeCo with CO was studied in a fixed‐bed reactor at 240 °C and 1.2 MPa. The initial CO2 conversion was found to be dependent on K loading, whereas both unpromoted and K‐promoted FeCo catalysts (except 90Fe10Co3.0K) exhibited similar levels of CO2 conversion after a few hours of time on stream. A decarburization study on freshly activated and used FeCo suggests that potassium increases the stability of iron carbides and graphitic carbon under a reducing atmosphere. Also, K addition tends to decrease the hydrogenation function of FeCo bimetallic catalysts and, thus, controls product selectivity. Under similar CO2 conversions, potassium enhanced acetic acid formation while suppressing ethanol production, which indicates that a common intermediate might be responsible for the changes observed with C2 oxygenates.

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“…In an early study, Stowe and Russell used cobalt, iron, and some of their alloys as catalysts for the hydrogenation of carbon dioxide. Satthawong et al .…”

Section: Introductionsupporting

confidence: 93%

Hydrogenation of Carbon Dioxide over K‐Promoted FeCo Bimetallic Catalysts Prepared from Mixed Metal Oxalates

et al. 2017

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“…Earlier research showed that bulk iron and iron oxides catalyze CO 2 hydrogenation, producing mainly methane. These catalysts were rapidly deactivated due to carbon deposition [11–12]. Doping with promoters such as potassium [13–18], manganese [19–21] and copper [22] had significant effect on both the reactivity and selectivity of the iron-based catalysts.…”

Section: Introductionmentioning

confidence: 99%

Carbon dioxide hydrogenation to aromatic hydrocarbons by using an iron/iron oxide nanocatalyst

Wang¹,

Hodgson²,

Shrestha³

et al. 2014

Beilstein J. Nanotechnol.

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SummaryThe quest for renewable and cleaner energy sources to meet the rapid population and economic growth is more urgent than ever before. Being the most abundant carbon source in the atmosphere of Earth, CO2 can be used as an inexpensive C1 building block in the synthesis of aromatic fuels for internal combustion engines. We designed a process capable of synthesizing benzene, toluene, xylenes and mesitylene from CO2 and H2 at modest temperatures (T = 380 to 540 °C) employing Fe/Fe3O4 nanoparticles as catalyst. The synthesis of the catalyst and the mechanism of CO2-hydrogenation will be discussed, as well as further applications of Fe/Fe3O4 nanoparticles in catalysis.

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“…Regarding the catalytic investigations, focus is put on the methane steam reforming and CO 2 methanation reactions, as only the combination of a catalytically active metal with these perovskites (LSF or STF) shows considerable activity and selectivity in the chosen reactions . The methanation reaction from CO (or CO 2 ) and H 2 to CH 4 or its reverse reaction, the methane steam reforming reaction, respectively, has been studied over a number of perovskite materials . The CO 2 methanation reaction in particular has attracted ongoing interest regarding energy‐efficient storage solutions for renewable electricity .…”

Section: Introductionmentioning

confidence: 99%

“…The CO 2 methanation reaction in particular has attracted ongoing interest regarding energy‐efficient storage solutions for renewable electricity . Thanks to the number of active catalysts (including transition metals such as Rh, Ru, Co, or Ni), the available literature on the methanation reaction is considerable . This also holds for the methane steam reforming reaction, which is also a well‐established method for efficient hydrogen production .…”

Section: Introductionmentioning

confidence: 99%

Rhodium‐Catalyzed Methanation and Methane Steam Reforming Reactions on Rhodium–Perovskite Systems: Metal–Support Interaction

et al. 2016

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Metal–support interaction in rhodium–perovskite systems was studied using LSF (La0.6Sr0.4FeO3−δ) and STF (SrTi0.7Fe0.3O3−δ) supports to disentangle different manifestations of strong or reactive metal–support interaction. Electron microscopy and catalytic characterization in methane steam reforming/CO2 methanation reveal that reduction in hydrogen at 673 K and 873 K causes different extents of Fe exsolution. Depending on the perovskite reducibility, Fe–Rh alloy particles are observed. No signs of strong metal–support interaction (i.e., encapsulation of metal particles) by reduced oxide species were observed. As re‐oxidation in oxygen at 873 K did not fully restore the initial structures, the interaction between Rh and the perovskites manifests itself in irreversible alloy formation. Catalytic effects are the suppression of methane reactivity with increasing prereduction temperature. The results show the limits of the strong metal–support interaction concept in complex metal–oxide systems.

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Cobalt, Iron and Some of their Alloys as Catalysts for the Hydrogenation of Carbon Dioxide¹

Cited by 15 publications

References 0 publications

Hydrogenation of Carbon Dioxide over K‐Promoted FeCo Bimetallic Catalysts Prepared from Mixed Metal Oxalates

Hydrogenation of Carbon Dioxide over K‐Promoted FeCo Bimetallic Catalysts Prepared from Mixed Metal Oxalates

Carbon dioxide hydrogenation to aromatic hydrocarbons by using an iron/iron oxide nanocatalyst

Rhodium‐Catalyzed Methanation and Methane Steam Reforming Reactions on Rhodium–Perovskite Systems: Metal–Support Interaction

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Cobalt, Iron and Some of their Alloys as Catalysts for the Hydrogenation of Carbon Dioxide1

Cited by 15 publications

References 0 publications

Hydrogenation of Carbon Dioxide over K‐Promoted FeCo Bimetallic Catalysts Prepared from Mixed Metal Oxalates

Hydrogenation of Carbon Dioxide over K‐Promoted FeCo Bimetallic Catalysts Prepared from Mixed Metal Oxalates

Carbon dioxide hydrogenation to aromatic hydrocarbons by using an iron/iron oxide nanocatalyst

Rhodium‐Catalyzed Methanation and Methane Steam Reforming Reactions on Rhodium–Perovskite Systems: Metal–Support Interaction

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Cobalt, Iron and Some of their Alloys as Catalysts for the Hydrogenation of Carbon Dioxide¹