Cobalt nitro complexes as oxygen transfer agents. 4. Epoxidation of olefins

Diamond, Steven; Mareš, F.; Szalkiewicz, Andrew; Muccigrosso, D. A.; Solar, Jeffrey P.

doi:10.1021/ja00379a046

Cited by 38 publications

(8 citation statements)

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“…The cobalt-nitrosyl complex can be reoxidized to the nitro complex by molecular oxygen. 304 The first step in the reaction depicted in Scheme 20 is probably a nucleophilic attack of one of the oxygens in the nitro group on the activated alkene in a similar way to the nucleophilic attack on metal-activated alkenes. 305 2.…”

Section: Co Rh and Irmentioning

confidence: 99%

Transition-metal-catalyzed epoxidations

Joergensen¹

1989

Chem. Rev.

1,055

391

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Section: Co Rh and Irmentioning

confidence: 99%

Transition-metal-catalyzed epoxidations

Joergensen¹

1989

Chem. Rev.

1,055

391

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“…"The Cl is performed for the ground state. 6These values are obtained by subtracting 0.7 (STO-3G level) and 0.5 kcal/mol (6-31G and 6-311G levels) from the total distortion energy of quadruplet allyl (see 14). "A£dis > 0 means reluctance to distort.…”

Section: See Ref 5m (B)mentioning

confidence: 99%

Is delocalization a driving force in chemistry? Benzene, allyl radical, cyclobutadiene, and their isoelectronic species

Shaik¹,

Hiberty²,

Lefour³

et al. 1987

J. Am. Chem. Soc.

242

153

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“…[44] Finally, during attempts to catalyse olefin amination, Diamonds and co-workers observed a new cyclization reaction leading to the formation of 2-methylquinoline. [45] Figure 4. [45] Figure 4.…”

Section: Nitrogen Donor Chelating Assistantsmentioning

confidence: 99%

Catalytic Formation of Carbon–Carbon Bonds by Activation of Carbon–Hydrogen Bonds

Guari

Sabo-Étienne

Chaudret³

1999

Eur. J. Inorg. Chem.

219

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The direct functionalization of C–H bonds by formation of a C–C bond is an interesting and important alternative to coupling reactions involving halide derivatives. These reactions are complex but during the past few years a number of new systems have been developed which display promising scope. This microreview will briefly mention the different mechanisms leading to C–H activation and describe the new systems leading to the catalytic formation of carbon–carbon bonds.

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Cobalt nitro complexes as oxygen transfer agents. 4. Epoxidation of olefins

Cited by 38 publications

References 0 publications

Transition-metal-catalyzed epoxidations

Transition-metal-catalyzed epoxidations

Is delocalization a driving force in chemistry? Benzene, allyl radical, cyclobutadiene, and their isoelectronic species

Catalytic Formation of Carbon–Carbon Bonds by Activation of Carbon–Hydrogen Bonds

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