Swift heavy ions induced structural and magnetic modifications of Co/Ti multilayers have been studied with 120 MeV Ag9+ ions at different ion fluences. The decrease in 1st Bragg peak intensity of X-ray reflectivity spectra confirms an increase in Co-Ti mixing at the interfaces, whereas X-ray diffraction (XRD) measurements reveal amorphization of the crystalline Co layer. XRD also indicates a shift in peak position towards a lower angle, confirming the development of tensile stress upon irradiation whereas an increase in the peak width suggests the reduction in the grain size. Vibrating sample magnetometer measurements show a reduction in Mr/Ms due to Co-Ti interface mixing and formed bcc-Co3Ti metastable phase. The X-ray absorption fine structure (XAFS) technique has been utilized to obtain variation in Co-Co and Co-Ti bond distances as a function of ion fluences. Quantitative estimation of Co3Ti phase generated due to ion irradiation has also been obtained using Co K-edge XAFS fitting.