Cocatalysis in phase-transfer catalyzed fluorination of alkyl halides and sulfonates

Mąkosza, Mieczysław; Bujok, Robert

doi:10.1016/j.jfluchem.2004.12.003

Cited by 30 publications

(12 citation statements)

References 19 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The latest published application of triorganotin(IV) fluorides, namely Ph 3 SnF, deals with liquid-solid phase-transfer catalyzed fluorinations of alkyl halides and sulfonates, where Ph 3 SnF acts as a phase-transfer catalyst via continuous formation of lipophilic Ph 3 SnF 2 À anions entering organic phase in the form of potassium salt [2][3][4].…”

Section: Introductionmentioning

confidence: 99%

Structure of N,C,N-chelated organotin(IV) fluorides

Novák

Cı́sařová²,

Kolářová³

et al. 2007

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

Section: Introductionmentioning

confidence: 99%

Structure of N,C,N-chelated organotin(IV) fluorides

Novák

Cı́sařová²,

Kolářová³

et al. 2007

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

“…Synthesis of fluorinated derivatives of monocarbonyl compounds, such as ketones and aldehydes, are of high importance in fluoro-organic chemistry [110][111][112][113][114][115][116][117][118][119][120][121]. These types of fluorinated derivatives are of proven synthetic value as building blocks for the preparation of a variety of polyfunctional fluorine-containing compounds of biological interest [30,[122][123][124][125][126][127][128].…”

Section: Fluorination Of Aryl-alkyl Ketonesmentioning

confidence: 99%

Kitamura Electrophilic Fluorination Using HF as a Source of Fluorine

et al. 2020

View full text Add to dashboard Cite

This review article focused on the innovative procedure for electrophilic fluorination using HF and in situ generation of the required electrophilic species derived from hypervalent iodine compounds. The areas of synthetic application of this approach include fluorination of 1,3-dicarbonyl compounds, aryl-alkyl ketones, styrene derivatives, α,β-unsaturated ketones and alcohols, homoallyl amine and homoallyl alcohol derivatives, 3-butenoic acids and alkynes.

show abstract

“…Notably, TBAT was shown to be not nearly as efficient a cocatalyst under conditions analogous to those used for the tin compounds. 53 …”

Section: Otbsmentioning

confidence: 99%