A branch of complex analysis with a rich history is geometric function theory, which first appeared in the early 20th century. The function theory deals with a variety of analytical tools to study the geometric features of complex-valued functions. The main purpose of this paper is to estimate more accurate bounds for the coefficient |an| of the functions that belong to a class of bi-univalent functions with missing coefficients that are defined by using the subordination. The significance of our present results consists of improvements to some previous results concerning different recent subclasses of bi-univalent functions, and the aim of this paper is to improve the results of previous outcomes. In addition, important examples of some classes of such functions are provided, which can help to understand the issues related to these functions.