HoTe3, a member of the rare-earth tritelluride (RTe3) family, and its Pd-intercalated compounds, PdxHoTe3, where superconductivity (SC) sets in as the charge-density wave (CDW) transition is suppressed by the intercalation of a small amount of Pd, are investigated using angle-resolved photoemission spectroscopy (ARPES) and electrical resistivity. Two incommensurate CDWs with perpendicular nesting vectors are observed in HoTe3 at low temperatures. With a slight Pd intercalation (x = 0.01), the large CDW gap decreases and the small one increases. The momentum dependence of the gaps along the inner Fermi surface (FS) evolves from orthorhombicity to near tetragonality, manifesting the competition between two CDW orders. At x = 0.02, both CDW gaps decreases with the emergence of SC. Further increasing the content of Pd for x = 0.04 will completely suppress the CDW instabilities and give rise to the maximal SC order. The evolution of the electronic structures and electron-phonon couplings (EPCs) of the multiple CDWs upon Pd intercalation are carefully scrutinized. We discuss the interplay between multiple CDW orders, and the competition between CDW and SC in detail. The recent observation of charge ordering in cuprate high-temperature superconductors 1,2 has reignited interests in CDW and its interplay with SC. A new charge ordering is always introduced by different types of instabilities, such as lattice distortion or FS nesting. However, the driving force behind the CDW phase is still under debate.3-15 From a Peierls perspective, in an ideal one-dimensional (1D) system, the electronic susceptibility would develop a logarithmic divergence singularity at some sheets of the FSs spanning by nesting vectors via EPCs, and hence results in a phase transition to the CDW ground state accompanied by the commensurate/incommensurate periodic lattice distortions and the opening of energy gaps at E F .3,4 Although, the quasi two-dimensional (2D) materials have a weaker tendency towards the nesting-driven CDWs owing to the imperfect nesting caused by the increased FS curvature, the electronic susceptibility could still be enhanced sufficiently for a CDW to develop under favorable nesting conditions and EPCs.16-19 Therefore, the CDW states in quasi 2D systems are particularly attractive due to the existence of possible multiple nesting properties and interacting collective orders added by the extra dimensionality.The fairly simple electronic structure of RTe 3 , where the CDW instabilities usually develop in the planar square nets of tellurium, 14 provides an unprecedented opportunity to systematically investigate the CDW formation and its relationship with FS nesting under pretty accurate theoretical models. An incommensurate CDW modulation characterized by a wave vector q 1 ≈ 2/7c * was commonly observed. [20][21][22][23] Recently, a second CDW transition occurs at lower temperatures with q 2 ≈ 1/3a * perpendicular to the first was discovered in heavier members of RTe 3 .19,23,24 Additionally, by the Pd intercalation, the suppres...