Stretchable electrodes are widely used in next-generation
wearable
electronics. Recent studies incorporated designs that help rigid electrodes
attain stretchability. However, these structures exhibited unsatisfactory
charge/signal extraction efficiency because of their low areal fill
factor. Additionally, they cannot be photolithographically patterned
on polymer substrates because of their low adhesion, requiring additional
complicated fabrication steps. We developed photolithographically
patternable stretchable electrodes with complete coverage and enhanced
charge-extraction efficiency. The electrodes, comprising double layers,
included a chemically treated Ag nanowire mesh and Au thin film. The
interfacial linker role of polyvinylpyrrolidone chemically strengthened
the interfacial bonds, and the reinforced concrete structure of nanowire-embedded
metal thin films enhanced the mechanical properties. Therefore, the
electrodes provided superior efficiency and stability in capturing
physical, electromagnetic, and electrophysiological signals while
exceeding the existing stretchable electrode limits. A broad range
of applications are foreseen, such as electrocardiogram sensing electrodes,
strain sensors, temperature sensors, and antennas.