Cold crystallization and photo-induced thermal behavior of alkyl-derivatized diarylethene molecules

Honda, Akinori; Ueno, Nachi; Fujiwara, Koki; Masuhara, Hirofumi; Miyamura, Kazuo

doi:10.1039/d2ra03898f

RSC Adv.

2022

DOI: 10.1039/d2ra03898f

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Cold crystallization and photo-induced thermal behavior of alkyl-derivatized diarylethene molecules

Akinori Honda

Nachi Ueno

Koki Fujiwara

et al.

Abstract: The alkylated diarylethene molecules exhibited cold crystallization, and their thermal behavior can be photo-controlled.

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2024

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All-Visible-Light-Activated Diarylethene Photoswitches

Li,

Ou,

Wen

et al. 2024

Molecules

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Photochromic compounds have attracted much attention for their potential applications in photo-actuators, optoelectronic devices and optical recording techniques. This interest is driven by their key photochemical and photophysical properties, which can be reversibly modulated by light irradiation. Among them, diarylethene compounds have garnered extensive investigation due to their excellent thermal stability of both open- and closed-form isomers, robust fatigue resistance, high photocyclization quantum yield and good photochromic performance in both solution and solid phases. However, a notable limitation in expanding the utility of diarylethene compounds is the necessity for ultraviolet light to induce their photochromism. This requirement poses challenges, as ultraviolet light can be detrimental to biological tissues, and its penetration is often restricted in various media. This review provides an overview of design strategies employed in the development of visible-light-responsive diarylethene compounds. These design strategies serve as a guideline for molecular design, with the potential to significantly broaden the applications of all-visible-light-activated diarylethene compounds in the realms of materials science and biomedical science.

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All-Visible-Light-Activated Diarylethene Photoswitches

Li,

Ou,

Wen

et al. 2024

Molecules

View full text Add to dashboard Cite

show abstract

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Cold crystallization and photo-induced thermal behavior of alkyl-derivatized diarylethene molecules

Abstract: The alkylated diarylethene molecules exhibited cold crystallization, and their thermal behavior can be photo-controlled.

Cited by 1 publication

References 40 publications

All-Visible-Light-Activated Diarylethene Photoswitches

All-Visible-Light-Activated Diarylethene Photoswitches

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