Modifications to the normal apparatus used for the cold vapor atomic absorption determination of mercury have been made by reducing the dead volume of the apparatus, by Increasing the efficiency of diffusion of elemental mercury into the carrier gas, and by optimizing the instrumental parameters. The time of analysis, the sample volume, and the detection limit have been greatly reduced. For a 1-ml sample, the concentration detection limit is 1 ppt of Hg(ll). The relative standard deviation for 0.05-10 ppb of Hg(ll) is approximately 3%. At concentrations below 0.05 ppb Hg(ll), imprecision is due mainly to the fluctuations from the radiation source; and, at concentrations above 0.05 ppb Hg(ll), sampling imprecision is limiting. To prevent mercury losses, an oxidizing agent and acid should be used as a preservative and, to prevent contamination, all glassware must be adequately cleaned with the oxidizing solution.