Various flooding
technologies were applied in the middle and late
stages of the oilfield, which made the heavy oil emulsion receive
much concern because of its high stability and separation difficulty.
In our paper, alcohol molecules were used as initiators and multibranched
block copolymers were synthesized through open-loop polymerization
technology. A variety of novel modified block polyether demulsifiers
with demulsification activity were finally synthesized through water-soluble
modification and oil-soluble modification, which achieved efficient
demulsification of heavy oil emulsions. Hydrophile–lipophile
balance (HLB) values and surface tension were used to characterize
demulsifiers. In addition, their demulsification efficiency was evaluated
by measuring the amount of dehydration in the separated heavy oil
emulsion experiments. The experimental results showed that within
5 h, the demulsification effect of the water-soluble demulsifier is
better than that of the oil-soluble demulsifier. When the HLB value
of the demulsifier reaches a certain value, the dehydration rate and
the demulsification effect reach the highest point. When the amount
of demulsifier is 50 μg/g and the demulsification temperature
is 85 °C, the dehydration rate of the water-soluble demulsifier
X-6 reached 91%, the water quality was clear, and the demulsification
effect reached its peak. This work will provide a novel and efficient
demulsifier for demulsification and dehydration of heavy oil emulsions.