In this paper, we consider the inverse problem of central configurations of n-body problem. For a given q = (q 1 , q 2 , . . . , q n ) ∈ (R d ) n , let S(q) be the admissible set of masses denotedThe main discovery in this paper is the existence of a singular curve¯ 31 on which S m (q) is a nonempty set for some m in the collinear four-body problem.¯ 31 is explicitly constructed by a polynomial in two variables. We proved:(1) If m ∈ S(q), then either # S m (q) = 0 or # S m (q) = 1.(2) # S m (q) = 1 only in the following cases: (i) If s = t, then S m (q) = {(m 4 , m 3 , m 2 , m 1 )}. (ii) If (s, t) ∈¯ 31 \ {(s,s)}, then either S m (q) = {(m 2 , m 4 , m 1 , m 3 )} or S m (q) = {(m 3 , m 1 , m 4 , m 2 )}.