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IntroductionColor centers in alkali-halide crystals are interesting for quantum optics, nano-optics, laser physics and other applications. They have long been studied and thoroughly investigated. There are a lot of reviews and monographs on this subject [1, 2]. However, most fluorescent studies in the 20th century were dedicated to the study of color centers on the ensemble level (that is fluorescence of a large number of centers was analyzed). With the development of single-molecule fluorescence microscopy [3], it became possible to examine individual quantum systems. This allows to get rid of averaging of properties over the ensemble, and thus to obtain new more detailed information. Apparently, the paper [4] was the first work in which a single color centers in crystals of lithium fluoride (F 2 centers) were used as light sources for scanning optical microscopy of high resolution. In [5] single color centers of the same type in the same crystal were studied by confocal scanning fluorescence microscopy for the first time.In this paper, we make an attempt to explore the reorientation of single F 2 centers in LiF crystals with laser scanning confocal fluorescence microscopy.