The thermal hysteresis behavior of La1/3Nd1/3Ca1/3MnO3 is investigated. An obvious thermal hysteresis in resistance occurs around the metal–semiconductor transition. The thermal hysteresis shows a strong thermal history dependent feature. Different resistivity loops, characterized by the temperature and resistivity corresponding to the transition, can be produced by cycling the sample following different thermal paths, resulting in a transition temperature varying from 90 to 104 K (in the cooling mode) and a corresponding peak resistivity ranging from 65.5 to 243 Ω cm. These behaviors are accompanied by a broad magnetic transition from a low moment state to a high moment state, with decreasing temperature, as well as a metamagnetic transition of the low moment state. A qualitative explanation of the present findings is provided.