2016
DOI: 10.1103/physrevlett.116.087003
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Colossal Seebeck Coefficient of Hopping Electrons in(TMTSF)2PF6

Abstract: We report on a study of the Seebeck coefficient and resistivity in the quasi-one-dimensional conductor (TMTSF)_{2} PF_{6} extended deep into the spin-density-wave state. The metal-insulator transition at T_{SDW}=12  K leads to a reduction in carrier concentration by 7 orders of magnitude. Below 1 K, charge transport displays the behavior known as variable range hopping. Until now, the Seebeck response of electrons in this regime has barely been explored and is even less understood. We find that, in this system… Show more

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Cited by 18 publications
(16 citation statements)
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“…The interest of the Aubry phase is related to high thermodynamic properties appearing in this phase. Thus we show that one can reach in this phase the high values of Seebeck coefficient S ≈ 50k B /e ≈ 4400µV/K which approaches to the record experimental values S ≈ 400k B /e observed in quasi-one-dimensional materials [44] and with two-dimensional electron gas in small disordered samples with S ∼ 50k B /e [45]. Even more remarkable is that in this phase the figure of merit can be as such high as ZT ≈ 8 being above the record experimental values [34].…”
Section: Discussionsupporting
confidence: 81%
“…The interest of the Aubry phase is related to high thermodynamic properties appearing in this phase. Thus we show that one can reach in this phase the high values of Seebeck coefficient S ≈ 50k B /e ≈ 4400µV/K which approaches to the record experimental values S ≈ 400k B /e observed in quasi-one-dimensional materials [44] and with two-dimensional electron gas in small disordered samples with S ∼ 50k B /e [45]. Even more remarkable is that in this phase the figure of merit can be as such high as ZT ≈ 8 being above the record experimental values [34].…”
Section: Discussionsupporting
confidence: 81%
“…This has been exemplified both experimentally and theoretically for quantum critical points in heavy fermions [1][2][3][4][5] , pnictides 6 , and for hole [7][8][9][10] , and electron-doped 11,12 cuprates. In organic superconductors like the Bechgaard salts (TMTSF) 2 X series, also known to exhibit quantum criticality, the measurements of the Seebeck coefficient have been the subject of numerous reports following their discovery [13][14][15][16][17][18][19] , and this, until very recently 20 . However, these works have found very little theoretical echo as to the possible part played by quantum fluctuations in the thermoelectric response seen in these correlated quasi-one dimensional (quasi-1D) metals.…”
Section: Introductionmentioning
confidence: 99%
“…The maximal value of S ∼ 12 obtained in this study is still smaller than the extreme values of S obtained in certain experiments. Thus in experiments with quasione-dimensional conductor (TMTSF) 2 PF 6 [37] as high as S = 400k B /e ≈ 35mV /K value had been reached at low temperatures (see Fig. 3 in [37]).…”
Section: Discussionmentioning
confidence: 94%