High-throughput
combinatorial investigations are transforming materials discovery,
phase diagram development, and processing optimization. Thin-film
deposition techniques are frequently used to fabricate sample libraries
employed in these studies. Various adaptations of well-known thin-film
chemical vapor deposition (CVD) and physical vapor deposition (PVD)
techniques utilized for the synthesis of inorganic combinatorial thin-film
materials libraries are reviewed, with novel processing approaches
being highlighted. Methods for developing gradients in composition
of other film properties are described. Issues and considerations
specific to thin-film processing of combinatorial materials libraries
are discussed, with some emphasis on catalytic applications.