Degradation and biodegradability enhancement of highly concentrated organic matter in the form of COD and color in ADSW treatment with microwave assisted ozone, and hydrogen peroxide was studied in laboratory scale experiment. The effects of corresponding effective factors, ozone (60 liter), H 2 O 2 (1ml of H2O2/100 ml ADSW) dose, MW treatment time (3min) optimized and used in experiment. The performance of all the three treatments was compare and measured in terms of percentage color, COD and BOD variation. For ozone treatment at 60 liter dose, reduction of 37.01% COD, color 64.75% and increase in BOD 64.75% was observed. Ozone in combination with H 2 O 2 remove 41.93% COD and color 70.28%. Alone MW treatment removes 19.35% COD remove and increase in BOD 20%. Combine ozone, H 2 O 2 and MW treatment shows more reduction COD 49.19%, color 36%, and BOD increase up to 56%, which shows the enhancement in biodegradability of ADSW.