2023
DOI: 10.1021/acs.inorgchem.3c01919
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Combined Experimental and Mechanoelastic Modeling Studies on the Low-Spin Stabilized Mixed Crystals of 3D Oxalate-Based Coordination Materials

Mousumi Dutta,
Shubham Bisht,
Prabir Ghosh
et al.

Abstract: Structural studies involving single-crystal and powder X-ray diffraction analysis have been performed on dehydrated coordination networks of the [Ni x Co 1−x (bpy) 3 ][LiCr(ox) 3 ] series, 0 ≤ x ≤ 1, (bpy = 2,2′-bipyridine). The high-symmetry cubic 3D structure of these materials is formed by oxalate anions bridging alternating Cr 3+ and Li + ions into an anionic framework, which contains large cavities that incorporate the [Ni x Co 1−x (bpy) 3 ] 2+ cations. Irrespective of the Co/Ni ratio, all of the mixed sa… Show more

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Cited by 2 publications
(2 citation statements)
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“…The Cr–S bonds have nearly identical distances (Figure ), and the peripheral N-cyano groups do not have any significant intermolecular interactions. This symmetric anionic unit could be used as a CP building block in a similar fashion to the well-utilized [M­(oxalate) 3 ] x – species; such efforts are currently in progress with this and the anionic Pb­(II) and Bi­(III)-based units described herein.…”
Section: Resultsmentioning
confidence: 99%
“…The Cr–S bonds have nearly identical distances (Figure ), and the peripheral N-cyano groups do not have any significant intermolecular interactions. This symmetric anionic unit could be used as a CP building block in a similar fashion to the well-utilized [M­(oxalate) 3 ] x – species; such efforts are currently in progress with this and the anionic Pb­(II) and Bi­(III)-based units described herein.…”
Section: Resultsmentioning
confidence: 99%
“…Solid solutions of SCO materials with isomorphous, inert dopants are an established tool for elucidating the lattice energetics of SCO processes. 38–55 We, and others, have also investigated doping as a way to introduce new functionality into SCO materials. 42,55–60 Two examples are particularly relevant to this work, where doping a complex into a host lattice changes its spin state properties.…”
Section: Introductionmentioning
confidence: 99%