2009
DOI: 10.1021/nl9006112
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Combining Pattern Instability and Shape-Memory Hysteresis for Phononic Switching

Abstract: We report a fully reversible and robust shape-memory effect in a two-dimensional nanoscale periodic structure composed of three steps, the elastic instability governing the transformation, the plasticity that locks in the transformed pattern as a result of an increase in glass transition temperature (T(g)), and the subsequent elastic recovery due to the vapor-induced decrease in T(g). Solvent swelling of a cross-linked epoxy/air cylinder structure induces an elastic instability that causes a reversible change … Show more

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Cited by 103 publications
(81 citation statements)
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References 24 publications
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“…Thus, this behavior provides opportunities for transformative materials with properties that can be reversibly switched. Similar instability induced pattern transformations have been observed also at the sub-micron scale [22,23] . These observations pave the way for the development of a new class of materials which take advantage of such behavior.…”
supporting
confidence: 80%
“…Thus, this behavior provides opportunities for transformative materials with properties that can be reversibly switched. Similar instability induced pattern transformations have been observed also at the sub-micron scale [22,23] . These observations pave the way for the development of a new class of materials which take advantage of such behavior.…”
supporting
confidence: 80%
“…In fact, an attempt has recently been made to synthesize materials that have submicron periodic structures with the capability of mechanical transformation [11,12]. However, the exact mechanism responsible for the change in structural colours of fish has not been fully understood, even for one of the most striking examples, the neon tetra (Paracheirodon innesi).…”
Section: Introductionmentioning
confidence: 99%
“…2A). This behavior has been demonstrated to provide opportunities for the design of materials with tunable negative Poisson's ratio [17], phonic switches [18] and strain-tunable optomechanical materials [19]. However, so far only the response of structures with circular and elliptical holes has been investigated and the effect of the pores shape on the structural response has not been explored yet.…”
mentioning
confidence: 99%