This
study investigated the ability of a five-component gasoline
surrogate (iso-octane, toluene, n-heptane, 1-hexene,
and ethanol) to replicate the combustion and knocking behavior of
a reference gasoline (PR5801 – RON 95.4, MON 86.6), under pressure
boosted spark-ignition engine conditions at various levels of blending
with iso-butanol. The ability of the neat surrogate was first evaluated
for stoichiometric air/fuel mixtures, at an intake temperature and
pressure of 320 K and 1.6 bar, respectively, and an end of compression
pressure of 30 bar, over a range of spark discharge timings. Throughout
this regime, the surrogate was found to produce a good representation
of the gasoline, particularly in terms of mean engine cycle properties,
knock onsets, and knock intensities. This high degree of similarity
between the surrogate and gasoline has also seen previous rapid compression
machine work, at comparable end-gas temperatures (Int. J. Chem.
Kinet.202153787808). However, significant differences were observed between the cyclic
variability of surrogate and gasoline results, which was attributed
to compositional differences between the two fuels. This study also
investigated the impact of iso-butanol blending (at ratios of 5–70%
iso-butanol by volume) on the performance of the gasoline at knocking
and nonknocking conditions, as well as the ability of the surrogate
to replicate the observed blending behavior, at the same experimental
conditions. In general, increasing the iso-butanol volume was shown
to decrease the knocking propensity of the fuel, except for a nonlinear
crossover behavior witnessed for 5% and 10% iso-butanol blends, wherein
the 5% blend became less reactive than the 10% blend due to the heavy
suppression of NTC behavior in the 10% blend. Even at such low concentrations,
iso-butanol appears to act as a strong radical sink, as identified
by brute-force sensitivity analysis of predicted knock onsets. This
is consistent with the findings of the aforementioned rapid compression
machine study. Blends of 20–50% iso-butanol were found to be
optimal for use in SI engines, providing considerable antiknock benefits
and comparable indicated power to gasoline, with blends of 20–30%
being the most viable due to the lower quantities of biofuel required.
Under blending with iso-butanol, the surrogate continued to perform
well, but blends were observably less reactive than the corresponding
gasoline blends at spark advance timings <8 °CA before top
dead center. The consistency found between trends within the literature
sourced rapid compression machine measurements, and engine data presented
in this study highlight the proficiency of fundamental measurements
in predicting combustion behavior within an engine at similar thermodynamic
conditions.