“…Atmospheric particles, soil, and sediments that are co-contaminated with toxic metals and polycyclic aromatic hydrocarbons (PAHs) have raised concerns due to their potential to cause combined adverse effects on human and ecological health. − The co-presence of toxic metals, especially some transition metals, may also change the particle properties, which, in turn, affects the transport, fate, and toxicity of PAHs and other organic pollutants. , For example, particulate matter containing chlorophenol and transition metal ions emitted from combustion sources in the atmosphere produces environmentally persistent free radicals (EPFRs) that may increase the human health risk of developing respiratory and cardiopulmonary diseases. − These types of EPFRs could also be observed during the oxidative decomposition of aromatic compounds (e.g., catechol and dibenzofuran). , The formation of EPFRs and their ecotoxicological effects in the natural environment have attracted increasing attention from scientists and public-health decision makers. , Fly ash and particulate matter contain organic contaminants and transition metals. As such, several studies have been conducted to understand combustion-related EPFRs on metal and mineral surfaces. − The role of transition-metal oxides on organic-contaminated surfaces in the formation and stabilization of combustion-generated EPFRs has been explored. − Progress has been made in these systems to characterize the electron transfer from organic molecules, especially chloro- and hydroxyl-substituted benzenes, to the metal and silica surfaces, resulting in the formation of EPFRs. − Comparatively, only limited studies have been performed examining the formation of EPFRs and their stabilization on contaminated soils at room temperature and also under environmental conditions. − …”