Entanglement is studied in the framework of Dyson's S-matrix theory in relativistic quantum field theory, which leads to a natural definition of entangled states of a particle-antiparticle pair and the spin operator from a Noether current. As an explicit example, the decay of a massive pseudo-scalar particle into a pair of electron and positron is analyzed. Two spin operators are extracted from the Noether current. The Wigner spin operator characterizes spin states at the rest frame of each fermion and, although not measurable in the laboratory, gives rise to a straightforward generalization of low-energy analysis of entanglement to the ultrarelativistic domain. In contrast, if one adopts a (modified) Dirac spin operator, the entanglement measured by spin correlation becomes maximal near the threshold of the decay, while the entanglement is replaced by the classical correlation for the ultrarelativistic electron-positron pair by analogy to the case of neutrinos, for which a hidden-variables type of description is possible. Chiral symmetry differentiates the spin angular momentum and the magnetic moment. The use of weak interaction that can measure helicity is suggested in the analysis of entanglement at high energies instead of a Stern-Gerlach apparatus, which is useless for the electron. A difference between the electron spin at high energies and the photon linear polarization is also noted. The Standard Model can describe all of the observable properties of leptons.