“…Bipolar electrochemistry, involving two driving electrodes and one conducting bipolar electrode (BPE) in electrolytic solution, has been a well-established technique since the 1960s, 30−33 but it attracted renewed interest and developed new applications 34−36 recently such as sensor development, 37−42 asymmetric synthesis, 43−47 micromotors, 46,48,49 and beyond. Because it has merits of wireless electrode, batching analysis ability, 37,50 exhibiting oxidation and reduction reaction simultaneously on BPE's counter ends, electrochemical gradients along the BPE, and ability of EC visualization, 16 there are lots of reports on developing BPE based sensing platforms using electrochemiluminescence (ECL), 39,40,51 fluorescence, or anodic electrochemical dissolution of metal layer 37,42,50 as reporter.…”