A novel chelating resin, crosslinking polystyrene-supported glucosamine (PS-GA), was prepared and its structure was confirmed by FTIR, elemental analysis, and X-ray photoelectron spectroscopy. The adsorption properties of PS-GA for Au(III) were investigated. PS-GA resin possessed excellent enriching property to Au(III) ions and adsorption proportion E% could reach to about 90 shortly after 3 h. The adsorption dynamics of Au(III) showed that the adsorption was controlled by liquid film diffusion and the apparent activation energy E a was 12.91 kJ mol
Ϫ1. BothLangmuir model and Freundlich model could describe the isothermal process of Au(III), and ⌬G, ⌬H, ⌬S values were calculated. The mechanism of adsorption for Au(III) was confirmed by FTIR, SEM, and XPS. The results showed that redox reaction occurred and both coordination and ionexchange existed simultaneously in the adsorption.