Comments on V. V. Nalimov recipient of the 1987 Derek de Solla Price award

Granovsky, Yu. V.

doi:10.1007/bf02021794

Cited by 5 publications

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“…For the four putative Ni tricarbonyl complexes used to computationally evaluate the Tolman electronic parameteri.e., ( i Pr 3 Sb)Ni(CO) 3 , ( i Pr 2 PhSb)Ni(CO) 3 , (Me 2 PhSb)Ni(CO) 3 , and (MePh 2 Sb)Ni(CO) 3 geometry optimizations were performed using the Firefly software package with the functional of mPW1PW91; the basis set of 6-31G(d) was used for H, C, and Ni; and TZP for Sb. IR calculations were accomplished using the same functional and basis sets.…”

Section: Methodsmentioning

confidence: 99%

Syntheses, Structures, and Characterization of Nickel(II) Stibines: Steric and Electronic Rationale for Metal Deposition

et al. 2018

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Reactions of the homoleptic and heteroleptic antimony ligands Sb Pr, Sb PrPh, SbMePh, and SbMePh with NiI generate rare Ni stibine complexes in either square planar or trigonal bipyramidal (TBP) geometries, depending on the steric size of the ligands. Tolman electronic parameters were calculated (DFT) for each antimony ligand to provide a tabulated resource for the relative strengths of simple antimony ligands. The electronic absorbance spectra of the square planar complexes exhibit characteristic bands [λ ≈ 560 nm (17 900 cm), ε ≈ 4330 M cm] at lower energies compared to the reported phosphine complexes, indicating the weak donor strength of the stibine ligands and resultant low-energy ligand field d→ d transitions. The square planar complex Ni(I)(Sb Pr) reacts with CO to form the TBP complex Ni(I)(Sb Pr)(CO). Lastly, the complexes were investigated for nickel metal deposition on Si|Cu(100 nm) substrates. The complexes with the strongest donating ligand, Sb Pr, deposited the purest layer of NiCu alloy according to the balanced reaction Ni(I)(SbPr) → Ni + Sb( Pr)I; the iodinated Sb byproduct was unambiguously detected in the supernatant by H NMR and mass spectrometry. Complexes with weaker ligands (poor I acceptors/scavengers) resulted undesired deposition of iodine and CuI on the surface. This work thus serves as a guide for the design and synthesis of 3 d metal complexes with neutral, heavy main-group donors that are useful for metal deposition applications.

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Section: Methodsmentioning

confidence: 99%

Syntheses, Structures, and Characterization of Nickel(II) Stibines: Steric and Electronic Rationale for Metal Deposition

et al. 2018

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“…In his presentation of the work of Nalimov, at the occasion of being the recipient of the 1987 Derek de Solla Price Award, Granovsky [11] wrote:…”

Section: Nalimovmentioning

confidence: 99%

Naukometriya, Nalimov and Mul’chenko

Rousseau

2021

COLLNET Journal of Scientometrics and Information Management

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In this article, we try to find out what Vasiliy Nalimov and Zinaida Mul'chenko exactly wrote in their famous book Naukometriya, the Study of the Development of Science as an Information Process (1969). Afterward, the term naukometriya became known in the West as scientometrics.It is often mentioned that Nalimov invented the term scientometrics, usually with reference to his book published in 1969. Shouldn't Mul'chenko be mentioned as one of the inventors of this term? We show that referring to Naukometriya is a case of wrong reference, as Nalimov introduced the term already in 1966.We further place the term scientometrics in the context of the science of science and of Soviet science during that period.

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The multidimensional space of Scientometrics; The Derek John de Solla Price awards 1984–1993

Bonitz¹

1994

Scientometrics

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Comments on V. V. Nalimov recipient of the 1987 Derek de Solla Price award

Cited by 5 publications

References 0 publications

Syntheses, Structures, and Characterization of Nickel(II) Stibines: Steric and Electronic Rationale for Metal Deposition

Syntheses, Structures, and Characterization of Nickel(II) Stibines: Steric and Electronic Rationale for Metal Deposition

Naukometriya, Nalimov and Mul’chenko

The multidimensional space of Scientometrics; The Derek John de Solla Price awards 1984–1993

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