Communication—Formation of a Hierarchical Reinforcing Carbon Fiber through Co-Grafting Graphene Oxide and Carbon Nanotube

Zhang, R. L.; Zhang, J.; Wang, C. G.; Li, F. H.; Liu, L.; Cui, Hongzhi

doi:10.1149/2.0201610jss

ECS J. Solid State Sci. Technol.

2016

DOI: 10.1149/2.0201610jss

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Communication—Formation of a Hierarchical Reinforcing Carbon Fiber through Co-Grafting Graphene Oxide and Carbon Nanotube

R. L. Zhang

J. Zhang

C. G. Wang

et al.

Abstract: Model polymer composites containing carbon nanotube (CNTs) and graphene oxide (GO) grafted carbon fiber provides a means to investigate the influence of nanostructures on interfacial properties. The morphology, together with the change of composition was related to the interfacial performance of model composites, which was studied using scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). In addition, the wetting and surface energy along with contact angles was explored using dynamic … Show more

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Cited by 4 publications

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“…1 Graphene-related materials are also postulated to be used in energy conversion and storage. 2 Thus, graphene and graphene-related materials have shown many applications in nanoelectronics, 3 sensors, 4 composite materials, 5 and in an environmental engineering. 6 Carbon and graphitic materials have also been for decades a workhorse material in electrochemistry.…”

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confidence: 99%

Synthesis of 3-D Graphene via Combustion Synthesis of Magnesium and Calcium/Magnesium Oxalates

Huczko

Kurcz

Dąbrowska

et al. 2017

ECS J. Solid State Sci. Technol.

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We demonstrate a novel and simple protocol for the fast and autothermal synthesis of layered graphene-related nanomaterial via the self-sustaining combustion synthesis. Various initial composition of starting reactants (Mg/CaC 2 O 4 and Mg/MgC 2 O 4 ) were tested and the effects of the operational parameters were systemically investigated in terms of the efficiency of product formation and its characteristics. The obtained products were analyzed using X-ray diffraction, electron microscopy, Raman spectroscopy and thermogravimetric analysis. The as-produced 3D graphene-related material has interesting properties and can be used in supercapacitors and as adsorbent for the removal of organic compounds. Graphene, a unique two-dimensional (2D) array of monolayer carbon atoms packed into a dense honeycomb crystal, has attracted much attention because of its diverse and extraordinary properties, i.e. electronic, magnetic, thermal, lubricant, chemical, optical, and mechanical.1 Graphene-related materials are also postulated to be used in energy conversion and storage.2 Thus, graphene and graphene-related materials have shown many applications in nanoelectronics, 3 sensors, 4 composite materials, 5 and in an environmental engineering.6 Carbon and graphitic materials have also been for decades a workhorse material in electrochemistry.7 Graphene was first produced by Novoselov et al. by mechanical exfoliation of graphite in 2004. 8 Since then many techniques have been proposed to obtain graphene with a main approach via energy-and timeconsuming wet chemistry route of graphite exfoliation. Jankovsky et al. 9 presented recently in details the thermal exfoliation/reduction of graphite oxide.The focus of this work is to obtain hierarchical layered carbons. Such few-layered graphene is also called 3D graphene 10 which, in fact, has many potential applications including energy storage (capacitors, electrodes), gas sensing, catalysis, biomedicine (biocompatible scaffolds), adsorption, hydrogels, and composites. As for example, Zhang et al. reported recently the synthesis of porous 3D graphene-based material with excellent properties for such applications. 11Herein we apply a self-propagating high-temperature synthesis (SHS), also called combustion synthesis (thermolysis) which has been widely used for years for fabrication of many compounds with large negative heat of formation.12,13 Such fast process usually progresses in a self-sustaining and energy self-efficient regime.7 In fact, we have shown elsewhere that SiC nanowires can be efficiently synthesized from simple starting reactants (Si/Teflon).14,15 Zhao et al. presented recently 16 an approach for synthesizing graphene through a magnesiothermic reduction of calcium carbonate, while Poh et al. 17 synthesized graphenes for electrochemical applications via reduction of CO 2 by lithium.The aim of this work was to test such a synthetic strategy for converting carbon-containing Ca/Mg oxalates into 3D graphene-related materials. The electrochemical measurements were performed to e...

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mentioning

confidence: 99%

Synthesis of 3-D Graphene via Combustion Synthesis of Magnesium and Calcium/Magnesium Oxalates

Huczko

Kurcz

Dąbrowska

et al. 2017

ECS J. Solid State Sci. Technol.

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Preparation of carbon nanotube/copper/carbon fiber hierarchical composites by electrophoretic deposition for enhanced thermal conductivity and interfacial properties

Yan

Liu

et al. 2018

J Mater Sci

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Positive synergistic effect of graphene oxide/carbon nanotube hybrid coating on glass fiber/epoxy interfacial normal bond strength

Yang

Liu

et al. 2017

Composites Science and Technology

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Communication—Formation of a Hierarchical Reinforcing Carbon Fiber through Co-Grafting Graphene Oxide and Carbon Nanotube

Cited by 4 publications

References 20 publications

Synthesis of 3-D Graphene via Combustion Synthesis of Magnesium and Calcium/Magnesium Oxalates

Synthesis of 3-D Graphene via Combustion Synthesis of Magnesium and Calcium/Magnesium Oxalates

Preparation of carbon nanotube/copper/carbon fiber hierarchical composites by electrophoretic deposition for enhanced thermal conductivity and interfacial properties

Positive synergistic effect of graphene oxide/carbon nanotube hybrid coating on glass fiber/epoxy interfacial normal bond strength

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