In this note we show that the second homotopy group of B(2, G), the classifying space for commutativity for a compact Lie group G, contains a direct summand isomorphic to π1(G) ⊕ π1([G, G]), where [G, G] is the commutator subgroup of G. It follows from a similar statement for E(2, G), the homotopy fiber of the canonical inclusion B(2, G) ֒→ BG. As a consequence of our main result we obtain that if E(2, G) is 2-connected, then [G, G] is simply-connected. This last result completes how the higher connectivity of E(2, G) resembles the higher connectivity of [G, G] for a compact Lie group G.