“…63,64 Inspired by the phenomenon of natural aggregation luminescence, 65 we previously synthesized oligomeric Ir photosensitizers via the copolymerization of [Ir(ppy) 2 (dabpy)](PF 6 ) with ODPA, which achieved a simultaneous increase in photocatalytic water splitting activity and stability due to the intramolecular interaction between adjacent [Ir(ppy) 2 (dabpy)](PF 6 ) molecules within the oligomer and the effect of large steric hindrance from the oligomer chains. 66 To further enhance the oligomeric structural effect on photocatalysis, herein, four kinds of oligomeric Ir photosensitizers were designed by tuning the structure of the anhydride linkers, namely (1,4,5,8-naphthalenetetracarboxylic dianhydride (NPTA), 3,3 0 ,4,4 0 -biphenyl tetracarboxylic dianhydride (BPDA), 4,4 0 -oxydiphthalic anhydride (ODPA), and hydroquinone diphthalic anhydride (HQDA)). The results show that in addition to the intramolecular interaction between adjacent [Ir(ppy) 2 (dabpy)](PF 6 ), oligomeric photosensitizers also aggregate with each other, which enables the coupling of neighboring oligomers through conformational adjustment.…”