Additive manufacturing (AM) of passive microwave components is of high interest for the costeffective and rapid prototyping or manufacture of devices with complex geometries. Here, we present an experimental study on the properties of recently demonstrated microwave resonator cavities manufactured by AM, in view of their applications to high-performance compact atomic clocks. The microwave cavities employ a loop-gap geometry using six electrodes. The critical electrode structures were manufactured monolithically using two different approaches: Stereolithography (SLA) of a polymer followed by metal coating and Selective Laser Melting (SLM) of aluminum. The tested microwave cavities show the desired TE 011 -like resonant mode at the Rb clock frequency of %6.835 GHz, with a microwave magnetic field highly parallel to the quantization axis across the vapor cell. When operated in an atomic clock setup, the measured atomic Rabi oscillations are comparable to those observed for conventionally manufactured cavities and indicate a good uniformity of the field amplitude across the vapor cell. Employing a time-domain Ramsey scheme on one of the SLA cavities, high-contrast (34%) Ramsey fringes are observed for the Rb clock transition, along with a narrow (166 Hz linewidth) central fringe. The measured clock stability of 2.2 Â 10 À13 s À1/2 up to the integration time of 30 s is comparable to the current state-of-the-art stabilities of compact vapor-cell clocks based on conventional microwave cavities and thus demonstrates the feasibil-ity of the approach.Compact microwave atomic clocks 1 based on alkali vapor cells 2,3 are widely employed as stable frequency references in numerous applications, ranging from telecommunication networks 4 to onboard clocks in satellite navigation systems. 5,6 In such atomic clocks, the frequency of a quartz local oscillator is stabilized to an inherently stable microwave transition in an alkali atom vapor held in a vapor cell. This greatly suppresses the quartz's fractional frequency instabilities to the 10 À12 to <10 À14 range (timing accuracies of 0.1 ls to <1 ns, respectively) over timescales up to one day. During the last decade, thanks to the employment of laser optical pumping, important advances were made in vapor-cell Rb atomic clocks based on the double-resonance (DR) scheme, using both the continuouswave (CW) 7 and the pulsed optical pumping (POP) interrogation (Ramsey scheme), 8,9 where the pulsed Ramsey scheme is of particular interest for highly compact and high-performance Rb cell clocks. In all types of DR atomic clocks, the microwave resonator cavity is a critical component for applying the microwave field to the atoms in a well-controlled geometry. In view of practical applications, this microwave cavity should be small and light-weight and feature simple and fast assembly. In DR atomic clocks, such cavities are generally manufactured by conventional subtractive precision machining of metals, often followed by time-consuming assembly steps requiring precise positioning or ali...